I can see some errors in catalina.log file, when the war file is being called, as tomcat is getting initialized:
Jan 30, 2014 3:02:39 PM org.apache.catalina.core.AprLifecycleListener init
INFO: The APR based Apache Tomcat Native library which allows optimal performance in production environments was not found on the java.library.path: C:\Program Files\Java\jre7\bin;C:\Windows\Sun\Java\bin;C:\Windows\system32;C:\Windows;C:\Program Files\ChemAxon\JChem\bin;C:\Windows\system32;C:\Windows;C:\Windows\System32\Wbem;C:\Program Files\Common Files\Acronis\SnapAPI\;C:\Windows\System32\WindowsPowerShell\v1.0\;.
Jan 30, 2014 3:02:42 PM org.apache.coyote.AbstractProtocol init
INFO: Initializing ProtocolHandler ["http-bio-8080"]
Jan 30, 2014 3:02:42 PM org.apache.coyote.AbstractProtocol init
INFO: Initializing ProtocolHandler ["ajp-bio-8009"]
Jan 30, 2014 3:02:42 PM org.apache.catalina.startup.Catalina load
INFO: Initialization processed in 4716 ms
Jan 30, 2014 3:02:42 PM org.apache.catalina.core.StandardService startInternal
INFO: Starting service Catalina
Jan 30, 2014 3:02:42 PM org.apache.catalina.core.StandardEngine startInternal
INFO: Starting Servlet Engine: Apache Tomcat/7.0.42
Jan 30, 2014 3:02:43 PM org.apache.catalina.startup.HostConfig deployWAR
INFO: Deploying web application archive C:\xampp\tomcat\webapps\webservices.war
Jan 30, 2014 3:04:16 PM org.apache.catalina.startup.ContextConfig processAnnotationsJar
SEVERE: Unable to process Jar entry [COM/ibm/db2os390/sqlj/custom/DB2SQLJCustomizer.class] from Jar [jar:file:/C:/xampp/tomcat/webapps/webservices/WEB-INF/lib/db2jcc-1.0.jar!/] for annotations
org.apache.tomcat.util.bcel.classfile.ClassFormatException: null is not a Java .class file
at org.apache.tomcat.util.bcel.classfile.ClassParser.readID(ClassParser.java:238)
at org.apache.tomcat.util.bcel.classfile.ClassParser.parse(ClassParser.java:114)
at org.apache.catalina.startup.ContextConfig.processAnnotationsStream(ContextConfig.java:2118)
at org.apache.catalina.startup.ContextConfig.processAnnotationsJar(ContextConfig.java:1994)
at org.apache.catalina.startup.ContextConfig.processAnnotationsUrl(ContextConfig.java:1960)
at org.apache.catalina.startup.ContextConfig.processAnnotations(ContextConfig.java:1945)
at org.apache.catalina.startup.ContextConfig.webConfig(ContextConfig.java:1319)
at org.apache.catalina.startup.ContextConfig.configureStart(ContextConfig.java:878)
at org.apache.catalina.startup.ContextConfig.lifecycleEvent(ContextConfig.java:376)
at org.apache.catalina.util.LifecycleSupport.fireLifecycleEvent(LifecycleSupport.java:119)
at org.apache.catalina.util.LifecycleBase.fireLifecycleEvent(LifecycleBase.java:90)
at org.apache.catalina.core.StandardContext.startInternal(StandardContext.java:5322)
at org.apache.catalina.util.LifecycleBase.start(LifecycleBase.java:150)
at org.apache.catalina.core.ContainerBase.addChildInternal(ContainerBase.java:901)
at org.apache.catalina.core.ContainerBase.addChild(ContainerBase.java:877)
at org.apache.catalina.core.StandardHost.addChild(StandardHost.java:633)
at org.apache.catalina.startup.HostConfig.deployWAR(HostConfig.java:976)
at org.apache.catalina.startup.HostConfig$DeployWar.run(HostConfig.java:1653)
at java.util.concurrent.Executors$RunnableAdapter.call(Unknown Source)
at java.util.concurrent.FutureTask.run(Unknown Source)
at java.util.concurrent.ThreadPoolExecutor.runWorker(Unknown Source)
at java.util.concurrent.ThreadPoolExecutor$Worker.run(Unknown Source)
at java.lang.Thread.run(Unknown Source)
Jan 30, 2014 3:04:16 PM org.apache.catalina.startup.ContextConfig processAnnotationsJar
SEVERE: Unable to process Jar entry [COM/ibm/db2os390/sqlj/custom/DB2SQLJEntryInfo.class] from Jar [jar:file:/C:/xampp/tomcat/webapps/webservices/WEB-INF/lib/db2jcc-1.0.jar!/] for annotations
org.apache.tomcat.util.bcel.classfile.ClassFormatException: null is not a Java .class file
at org.apache.tomcat.util.bcel.classfile.ClassParser.readID(ClassParser.java:238)
at org.apache.tomcat.util.bcel.classfile.ClassParser.parse(ClassParser.java:114)
at org.apache.catalina.startup.ContextConfig.processAnnotationsStream(ContextConfig.java:2118)
at org.apache.catalina.startup.ContextConfig.processAnnotationsJar(ContextConfig.java:1994)
at org.apache.catalina.startup.ContextConfig.processAnnotationsUrl(ContextConfig.java:1960)
at org.apache.catalina.startup.ContextConfig.processAnnotations(ContextConfig.java:1945)
at org.apache.catalina.startup.ContextConfig.webConfig(ContextConfig.java:1319)
at org.apache.catalina.startup.ContextConfig.configureStart(ContextConfig.java:878)
at org.apache.catalina.startup.ContextConfig.lifecycleEvent(ContextConfig.java:376)
at org.apache.catalina.util.LifecycleSupport.fireLifecycleEvent(LifecycleSupport.java:119)
at org.apache.catalina.util.LifecycleBase.fireLifecycleEvent(LifecycleBase.java:90)
at org.apache.catalina.core.StandardContext.startInternal(StandardContext.java:5322)
at org.apache.catalina.util.LifecycleBase.start(LifecycleBase.java:150)
at org.apache.catalina.core.ContainerBase.addChildInternal(ContainerBase.java:901)
at org.apache.catalina.core.ContainerBase.addChild(ContainerBase.java:877)
at org.apache.catalina.core.StandardHost.addChild(StandardHost.java:633)
at org.apache.catalina.startup.HostConfig.deployWAR(HostConfig.java:976)
at org.apache.catalina.startup.HostConfig$DeployWar.run(HostConfig.java:1653)
at java.util.concurrent.Executors$RunnableAdapter.call(Unknown Source)
at java.util.concurrent.FutureTask.run(Unknown Source)
at java.util.concurrent.ThreadPoolExecutor.runWorker(Unknown Source)
at java.util.concurrent.ThreadPoolExecutor$Worker.run(Unknown Source)
at java.lang.Thread.run(Unknown Source)
Jan 30, 2014 3:04:16 PM org.apache.catalina.startup.ContextConfig processAnnotationsJar
SEVERE: Unable to process Jar entry [COM/ibm/db2os390/sqlj/custom/DB2SQLJProfile.class] from Jar [jar:file:/C:/xampp/tomcat/webapps/webservices/WEB-INF/lib/db2jcc-1.0.jar!/] for annotations
org.apache.tomcat.util.bcel.classfile.ClassFormatException: null is not a Java .class file
at org.apache.tomcat.util.bcel.classfile.ClassParser.readID(ClassParser.java:238)
at org.apache.tomcat.util.bcel.classfile.ClassParser.parse(ClassParser.java:114)
at org.apache.catalina.startup.ContextConfig.processAnnotationsStream(ContextConfig.java:2118)
at org.apache.catalina.startup.ContextConfig.processAnnotationsJar(ContextConfig.java:1994)
at org.apache.catalina.startup.ContextConfig.processAnnotationsUrl(ContextConfig.java:1960)
at org.apache.catalina.startup.ContextConfig.processAnnotations(ContextConfig.java:1945)
at org.apache.catalina.startup.ContextConfig.webConfig(ContextConfig.java:1319)
at org.apache.catalina.startup.ContextConfig.configureStart(ContextConfig.java:878)
at org.apache.catalina.startup.ContextConfig.lifecycleEvent(ContextConfig.java:376)
at org.apache.catalina.util.LifecycleSupport.fireLifecycleEvent(LifecycleSupport.java:119)
at org.apache.catalina.util.LifecycleBase.fireLifecycleEvent(LifecycleBase.java:90)
at org.apache.catalina.core.StandardContext.startInternal(StandardContext.java:5322)
at org.apache.catalina.util.LifecycleBase.start(LifecycleBase.java:150)
at org.apache.catalina.core.ContainerBase.addChildInternal(ContainerBase.java:901)
at org.apache.catalina.core.ContainerBase.addChild(ContainerBase.java:877)
at org.apache.catalina.core.StandardHost.addChild(StandardHost.java:633)
at org.apache.catalina.startup.HostConfig.deployWAR(HostConfig.java:976)
at org.apache.catalina.startup.HostConfig$DeployWar.run(HostConfig.java:1653)
at java.util.concurrent.Executors$RunnableAdapter.call(Unknown Source)
at java.util.concurrent.FutureTask.run(Unknown Source)
at java.util.concurrent.ThreadPoolExecutor.runWorker(Unknown Source)
at java.util.concurrent.ThreadPoolExecutor$Worker.run(Unknown Source)
at java.lang.Thread.run(Unknown Source)
Jan 30, 2014 3:05:13 PM org.apache.catalina.startup.HostConfig deployDirectory
INFO: Deploying web application directory C:\xampp\tomcat\webapps\docs
Jan 30, 2014 3:05:13 PM org.apache.catalina.startup.HostConfig deployDirectory
INFO: Deploying web application directory C:\xampp\tomcat\webapps\examples
Jan 30, 2014 3:05:15 PM org.apache.catalina.startup.HostConfig deployDirectory
INFO: Deploying web application directory C:\xampp\tomcat\webapps\host-manager
Jan 30, 2014 3:05:15 PM org.apache.catalina.startup.HostConfig deployDirectory
INFO: Deploying web application directory C:\xampp\tomcat\webapps\manager
Jan 30, 2014 3:05:16 PM org.apache.catalina.startup.HostConfig deployDirectory
INFO: Deploying web application directory C:\xampp\tomcat\webapps\ROOT
Jan 30, 2014 3:05:16 PM org.apache.coyote.AbstractProtocol start
INFO: Starting ProtocolHandler ["http-bio-8080"]
Jan 30, 2014 3:05:16 PM org.apache.coyote.AbstractProtocol start
INFO: Starting ProtocolHandler ["ajp-bio-8009"]
Jan 30, 2014 3:05:16 PM org.apache.catalina.startup.Catalina start
INFO: Server startup in 154149 ms