plugin for Markov. with same H count for non-aromatics

User b7aa615db3

08-06-2005 23:37:09

Is there a plugin that can be used to create a Markovnikov reaction in the case when the hCount() is the same for both (non-aromatic) carbons? I see plugins that might be appropriate for aromatic atoms, but not non-aromatic.

ChemAxon d76e6e95eb

10-06-2005 13:53:53

Try the sigma component of the partial charge on the carbons (requires charge plugin license). Try a SELECTIVITY rule like this (depending on your schema and mapping):





Code:
charge(ratom(2), "sigma")






If it does not help, then please show me a sample reaction you would like to process and also the reaction definition which is not sufficient for you at the moment.