Mesomerize/Neutralize sequence on iminium ions = reduction

User 81a38f9467

14-02-2011 23:00:36

I am using the standalone Standardizer version 5.4.0.1.


The Mesomerize function followed by Neutralize leads to a net reduction of the double bond.  This should not occur.   Mesomerize leads to a carbenium ion (which is wrong) and "neutralization" of the carbenium ion apparently involves hydride addition.  Thus it appears that both steps lead to incorrect outputs. 

User 851ac690a0

19-02-2011 00:06:20

Hi,


Yes, this is a bug. We will fix asap.


Thank you for reporting.    


 


Jozsi